Experiment 1: Butterfly Pea Powder, Part 1

Experiment 1: Butterfly Pea Powder, Part 1

Did you know that, under the right conditions, some plants can change color? The butterfly pea flower is one of those, and I've heard that it can be used to color baked goods. So, I designed an experiment to try it. 

Some background: Powdered butterfly pea flowers typically have a deep blue color when mixed into drinks and baked goods. However, in acidic conditions, it changes to a nice purple. Under basic conditions, it becomes more green. This happens because of changes in the balance between the different forms of the molecule responsible for the color. In neutral conditions, there's a pretty equal balance of the red and blue forms of this molecule. When the pH is lowered and the solution becomes more acidic, that balance is pushed towards the red form, causing the color to become more purple. When the pH gets higher and the solution becomes basic, the balance shifts towards the yellow form and the color shows up more green. If you think this color-changing property is super cool and want to read more about the science, here is a very interesting article.

Figure 2. The four main forms of anthocyanins at varying pH.

 

So, my experiments had two purposes. First, I wanted to test how well a powdered flower would color macaron shells. Second, I wanted to see the color-changing properties in action.

My macaron process always begins with getting all my ingredients prepped: separating eggs, weighing sugar, and sifting together almond flour and powdered sugar. For this batch, I knew that, in order for the color to change the way I wanted, I needed to make my batter mixture acidic, so I used a French meringue and added a pinch of cream of tartar (pH = 3.5) to my sugar. 

Once I had all of my ingredients ready, I started mixing. I threw the egg whites straight into the mixer bowl, and for my experiment, I added about an eighth teaspoon of the butterfly pea powder in right away (my first mistake).  

The color started out as exactly what I was expecting: a nice, deep blue. However, not all the powder was fully mixing in. It was a little clumpy, and I realized I maybe should have sifted it or at least broken up the bigger clumps before adding to the egg whites. But it was too late, so I left it to mix, hoping the clumps would dissolve as the meringue whipped. 

Anyways, after the meringue whipped for a few minutes, I added the sugar and cream of tartar, and that's when things started to get interesting. See, I was expecting the acidity from the cream of tartar to shift the color towards purple, but actually the opposite happened. It started to turn green.

My first thought was that maybe there wasn't enough cream of tartar to turn it purple. But then I did some thinking, and some research, and realized I had made a fatal mistake. I had forgotten to consider the pH of the egg whites. Egg whites are quite basic (pH = around 9), which would definitely be enough to push the color into the green range.

As the meringue finished whipping, the color faded to a pale blue. It was a nice color, but definitely not the result I was hoping for. 
I finished mixing the batter, piped it out, and let it rest. The addition of the dry ingredients turned the batter slightly gray, but I actually wasn't too disappointed with the color. Again, definitely not what I was going for, but not bad. Until they baked.
They spread, faded and browned at the same time, the feet were ugly, and they were hollow. Overall, bad ending.

So, even though this first experiment was a failure, I gained some insight and learned a lot of things that will help next time. For example, don't forget to think about the pH of your main ingredient when your experiment literally depends on it.
Back to blog